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91.
G. T. Jones R. W. L. Jones B. W. Kennedy D. R. O. Morrison D. B. Miller M. M. Mobayyen S. Wainstein M. Aderholz D. Hantke U. F. Katz J. Kern N. Schmitz W. Wittek H. P. Borner G. Myatt F. W. Bullock S. Burke 《Zeitschrift fur Physik C Particles and Fields》1993,58(3):375-386
Evidence is presented for diffractive production of -mesons and of -systems invp and
chargedcurrent interactions. In the (anti-)neutrino energy range 10 GeVE
v
<60 gev=" the=" cross=" sections=" for=" diffractive=">60> and diffractive production are found to be (0.64±0.14 (stat.)±0.08 (syst.))% and (0.28±0.08 (stat.)±0.04 (syst.))% of the charged-current cross section. The diffractive signal is consistent with being entirely due to diffractivea
1 production. However, the data cannot distinguish between diffractivea
1 and diffractive nonresonant production. The experimental distributions ofW, Q
2,x
Bj
andy
Bj
for diffractive and events are consistent with model predictions. 相似文献
92.
93.
Abe K Abt I Acton PD Agnew G Ash WW Aston D Bacchetta N Baird KG Baltay C Band HR Baranko G Bardon O Battiston R Bazarko AO Bean A Belcinski RJ Ben-David R Benvenuti AC Biasini M Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Carr J Cassell R Castaldi R Castro A Cavalli-Sforza M Chadwick GB Chen L Church E Claus R Cohn HO Coller JA Cook V Cotton R 《Physical review letters》1993,71(16):2528-2532
94.
95.
Emil Pop Marcus E. Brewster J. J. Kaminski Nicholas Bodor 《International journal of quantum chemistry》1989,35(2):315-324
9-Amino-1,2,3,4-tetrahydroacridine (THA ), a potent cholinesterase inhibitor, was recently used in the treatment of Alzheimer's disease. On attempting to prepare a dihydropyridine ? pyridinium salt-based redox chemical delivery system (CDS ) to enhance brain delivery of THA , several of the practical synthetic challenges were examined by using a theoretical MO approach. The structures, reactivities and stability of THA , derivatives of THA and a model compound, 4-aminopyridine, a simple dibasic heterocyclic amine, were studied in the framework of the AM -1 approximation. The study included the possible protonated forms of THA and 4-aminopyridine. The calculated heats of formation showed that ring nitrogen protonated forms are more stable for both THA and 4-aminopyridine. The calculated heats of formation showed that ring nitrogen protonated forms are more stable for both THA and 4-aminopyridine, consistent with experimental results. Electron delocalization is responsible for the remarkable stability of these molecules and for the observed lack of reactivity of the amino group, both in the basic and protonated forms. The site of N-alkylation of the 9-nicotinamide derivative of THA (an intermediate in the synthesis of THA -CDS ) is controlled by electronic, thermodynamic, and steric factors. 相似文献
96.
Using recently developed theoretical techniques it has been possible to achieve an exact variational solution of the Schrödinger equation within a modest basis set or one-eleltron functions. The full configuration interaction for this system included a total of 256473 1A1 spin-and space-adapted configurations. Comparison with many-body perturbation theory proves to be quite interesting. 相似文献
97.
We report on phototriggered Ru-S --> Ru-O and thermal Ru-O --> Ru-S intramolecular linkage isomerizations in cis- and trans-[Ru(bpy)2(dmso)2]2+. The cis complex features only S-bonded sulfoxides (cis-[S,S]), whereas the trans isomer is characterized by S- and O-bonded dmso ligands. Both cis-[S,S] and trans-[S,O] exhibit photochromism at room temperature in dmso solution and ionic liquid (IL). Rates of reaction in IL were monitored by UV-visible spectroscopy and are similar to those reported in dmso solution (k(O-->S) ranges from approximately 10(-3) to 10(-4) s(-1)). Cyclic voltammetric measurements of cis-[S,S] and trans-[S,O] are consistent with an electrochemically triggered linkage isomerism mechanism. While both cis-[S,S] and trans-[S,O] are photochromic at room temperature, neither complex is emissive. However, upon cooling to 77 K, cis-[S,S] exhibits LMCT (ligand-to-metal charge transfer) emission typical of many ruthenium polypyridine complexes. In contrast to cis-[S,S], trans-[S,O] does not show any detectable emission even at 77 K. 相似文献
98.
99.
de la Vaissiere C Luth V Abrams GS Amidei D Baden AR Barklow T Boyarski AM Boyer J Breidenbach M Burchat P Burke DL Butler F Dillon JW Dorfan JM Feldman GJ Gidal G Gladney L Gold MS Goldhaber G Golding LG Hanson G Haggerty J Herrup D Himel T Hollebeek RJ Innes WR Jaros JA Juricic I Kadyk JA Klein SR Lankford AJ Larsen RR LeClaire BW Levi ME Lockyer NS Matteuzzi C Nelson ME Ong RA Perl ML Richter B Ross MC Rowson PC Schaad T Schellman H Schmidke WB Sheldon PD Trilling GH Yelton JM Wood DR 《Physical review letters》1985,54(19):2071-2074
100.
Multivalent cations can cause DNA to condense from its extended state in solution into high-density toroid-shaped particles. Developing methods to control the size and size distribution of DNA toroids is an important goal for the development of artificial gene delivery systems. Here we demonstrate that changes in salt conditions, prior to condensation by multivalent cations, can significantly affect DNA condensation. Specifically, millimolar concentrations of MgCl2 are shown to cause the formation of toroid clusters, whereas NaCl at the same ionic strength does not. 相似文献